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Lava worlds are a potential emerging population of Super-Earths that are on close-in orbits around their host stars, with likely partially molten mantles. To date, few studies have addressed the impact of magma on the observed properties of a planet. At ambient conditions, magma is less dense than solid rock; however, it is also more compressible with increasing pressure. Therefore, it is unclear how large-scale magma oceans affect planet observables, such as bulk density. We updateExoPlex, a thermodynamically self-consistent planet interior software, to include anhydrous, hydrous (2.2 wt% H₂O), and carbonated magmas (5.2 wt% CO₂). We find that Earth-like planets with magma oceans larger than ∼1.5R_⊕and ∼3.2M_⊕are modestly denser than an equivalent-mass solid planet. From our model, three classes of mantle structures emerge for magma ocean planets: (1) a mantle magma ocean, (2) a surface magma ocean, and (3) one consisting of a surface magma ocean, a solid rock layer, and a basal magma ocean. The class of planets in which a basal magma ocean is present may sequester dissolved volatiles on billion-year timescales, in which a 4M_⊕mass planet can trap more than 130 times the mass of water than in Earth’s present-day oceans and 1000 times the carbon in the Earth’s surface and crust.

 

We present a reanalysis of the K2-106 transiting planetary system, with a focus on the composition of K2-106b, an ultra-short-period, super-Mercury candidate. We globally model existing photometric and radial velocity data and derive a planetary mass and radius for K2-106b of Mp = 8.53 ± 1.02 M⊕ and = - + Rp 1.71 0.057 RÅ 0.069 , which leads to a density of r = - + 9.4 p 1.5 1.6 g cm−3 , a significantly lower value than previously reported in the literature. We use planet interior models that assume a two-layer planet comprised of a liquid, pure Fe core and an iron-free, MgSiO3 mantle, and we determine that the range of the core mass fractions are consistent with the observed mass and radius. We use existing high-resolution spectra of the host star to derive the Fe/Mg/Si abundances ([Fe/ H] = −0.03 ± 0.01, [Mg/H] = 0.04 ± 0.02, [Si/H] = 0.03 ± 0.06) to infer the composition of K2-106b. We find that K2-106b has a density and core mass fraction ( - + 44 %15 12 ) consistent with that of Earth (CMF⊕ = 32%). Furthermore, its composition is consistent with what is expected, assuming that it reflects the relative refractory abundances of its host star. K2-106b is therefore unlikely to be a super-Mercury, as has been suggested in previous literature. 

The degree to which the Earth’s mantle stores and cycles water in excess of the storage capacity of nominally anhydrous minerals is dependent upon the stability of hydrous phases under mantle-relevant pressures, temperatures, and compositions. Two hydrous phases, phase D and phase H, are stable to the pressures and temperatures of the Earth’s lower mantle, suggesting that the Earth’s lower mantle may participate in the cycling of water. We build on our prior work of density functional theory calculations on phase H with the stability, structure, and bonding of hydrous phases D, and we predict the aluminum partitioning with H in the Al 2 O 3 -SiO 2 -MgO-H 2 O system. We address the solid solutions through a statistical sampling of site occupancy and calculation of the partition function from the grand canonical ensemble. We show that each phase has a wide solid solution series between MgSi 2 O 6 H 2 -Al 2 SiO 6 H 2 and MgSiO 4 H 2 -2 δ AlOOH + SiO 2 , in which phase H is more aluminum rich than phase D at a given bulk composition. We predict that the addition of Al to both phases D and H stabilizes each phase to higher temperatures through additional configurational entropy. While we have shown that phase H does not exhibit symmetric hydrogen bonding at high pressure, we report here that phase D undergoes a gradual increase in the number of symmetric H-bonds beginning at ∼30 GPa, and it is only ∼50% complete at 60 GPa. 

Phase egg, [AlSiO3(OH)], is an aluminosilicate hydrous mineral that is thermodynamically stable in lithological compositions represented by Al2O3-SiO2-H2O (ASH) ternary, i.e., a simplified ternary for the mineralogy of subducted sediments and continental crustal rocks. High-pressure and high-temperature experiments on lithological compositions resembling hydrated sedimentary layers in subducting slabs show that phase egg is stable up to pressures of 20–30 GPa, which translates to the transition zone to lower mantle depths. Thus, phase egg is a potential candidate for transporting water into the Earth’s mantle transition zone. In this study, we use first-principles simulations based on density functional theory to explore the pressure dependence of crystal structure and how it influences energetics and elasticity. Our results indicate that phase egg exhibits anomalous behavior of the pressure dependence of the elasticity at mantle transition zone depths (~15 GPa). Such anomalous behavior in the elasticity is related to changes in the hydrogen bonding O-H···O configurations, which we delineate as a transition from a low-pressure to a high-pressure structure of phase egg. Full elastic constant tensors indicate that phase egg is very anisotropic resulting in a maximum anisotropy of compressional wave velocity, AvP ≈ 30% and of shear wave velocity, AvS ≈ 17% at zero pressures. Our results also indicate that the phase egg has one of the fastest bulk sound velocities (vP and vS) compared to other hydrous aluminous phases in the ASH ternary, which include topaz-OH, phase Pi, and d-AlOOH. However, the bulk sound velocity of phase egg is slower than that of stishovite. At depths corresponding to the base of mantle transition zone, phase egg decomposes to a mixture of d-AlOOH and stishovite. The changes in compressional DvP and shear DvS velocity associated with the decomposition is ~0.42% and –1.23%, respectively. Although phase egg may be limited to subducted sediments, it could hold several weight percentages of water along a normal mantle geotherm.